New wrinkle in the mystery of high-Tc superconductors

In the twenty years since the discovery of high-temperature (Tc) superconductors, scientists have been trying to understand the mechanism by which electrons pair up and move coherently to carry electrical current with no resistance. "We are still at the beginning," says Tonica Valla, a physicist at the U.S. Department of Energy's Brookhaven National Laboratory, who will give a talk on his group's latest results at the American Physical Society meeting in Baltimore, Maryland on Thursday, March 16, 2006. "If anything," he adds, "it looks like the story is getting more complicated."

In 1999, Valla's group was the first to observe a "kink" in the energy level of electrons in high-Tc superconductors just as they went through the transition temperature from their normal to superconducting state. The kink was the first clue to explaining what the mechanism of electron pairing might be.

"The kink gave us the hope that we could identify the interaction that was responsible for the electron pairing," said Valla. Some groups hold that the mechanism is the same as in conventional superconductors -- that is, that phonons, or vibrations in the crystal lattice, are responsible for electron pairing. Other scientists believe that changes in the spin alignment, or magnetic polarity, of adjacent electrons -- known as magnons -- are responsible. "The problem is that there are both phonons and magnons in the crystal with the energy where we see the kink, so it is still not clear," Valla says.

The latest wrinkle uncovered by Valla's group is the observation of similar energy scales and gaps in a material that is not a superconductor. The material is a special form of a compound made of lanthanum, barium, copper, and oxygen, where there is exactly one barium atom for every eight copper atoms. With less or more barium, the material acts as a high-Tc superconductor (in fact, this was the very first high-Tc superconductor discovered). But at the 1:8 ratio, the material momentarily loses its superconductivity.

"The fact that this system, which is not a superconductor, has similar properties to the superconducting system is not helping to solve the mystery," Valla says. But then he notes that 20 years since the discovery of high-Tc superconductors is still not that long. "For conventional superconductors," he says, "it took about 50 years to come up with a good explanation for the behavior."

Valla's talk is part of a session on the use of angle-resolved photoemission spectroscopy in the study of high-Tc superconductors. It will include a discussion of advances in this technique. His group uses bright beams of ultraviolet light at the National Synchrotron Light Source, one of Brookhaven Lab's premiere research facilities, to emit electrons from the samples they are studying. Using high-resolution spectrometers, the scientists measure the energy and the angle at which the electrons exit the crystal, allowing them to reconstruct the electrons' state while in the crystal -- their energy level and whether they had any interactions with phonons/magnons.

The talk will take place on Thursday, March 16, 2006 at 3:06 p.m. in Ballroom IV of the Baltimore Convention Center.

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This research was funded by the Office of Basic Energy Sciences within the U.S. Department of Energy's Office of Science. The Department of Energy has a keen interest in understanding the mechanisms of superconducting materials -- particularly those that can carry current with zero resistance at higher temperatures -- because these materials have many potential applications in improving the efficiency of energy generation and transmission.

Note to local editors: Tonica Valla lives in East Setauket, New York. One of ten national laboratories overseen and primarily funded by the Office of Science of the U.S. Department of Energy (DOE), Brookhaven National Laboratory conducts research in the physical, biomedical, and environmental sciences, as well as in energy technologies and national security. Brookhaven Lab also builds and operates major scientific facilities available to university, industry and government researchers. Brookhaven is operated and managed for DOE's Office of Science by Brookhaven Science Associates, a limited-liability company founded by the Research Foundation of State University of New York on behalf of Stony Brook University, the largest academic user of Laboratory facilities, and Battelle, a nonprofit, applied science and technology organization. Visit Brookhaven Lab's electronic newsroom for links, news archives, graphics, and more: http://www.bnl.gov/newsroom


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